Product ID:4301, PETROLEUM BASED PAINT
MSDS Date:09/21/1987
FSC:8010
NIIN:00N060918
MSDS Number: BYSRZ

VALVOLINE OIL CO

ASHLAND, KY 41114
US

Emergency Phone: 606-324-1133

Info Phone: 606-329-3333

Cage: DO734

VALVOLINE OIL COMPANY

14000 ASHLAND, KY 41114 US

Telephone: 606-324-1133

Cage: DO734

ASPHALT

CAS: 64742-93-4

Fraction By Weight: 55-60%

OSHA PEL N/K

ACGIH TLV: N/K

STODDARD SOLVENT;(ALIPHATIC PETROLEUM DISTILLATES)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 35-40%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

NO 2 FUEL OIL;(ALIPHATIC PETROLEUM DISTILLATES)

CAS: 68476-30-2

RTECS: LS8930000

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL

RTECS: 9999999ZZ

LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR

RTECS: 9999999ZZ

RUN-OFF TO SEWERS, STREAMS/OTHER BODIES OF WATER. IF

RTECS: 9999999ZZ

SPILL HAS OCCURED.

RTECS: 9999999ZZ

EQUIP SUPPLIER). ENGINEERING/ADMIN CONTROLS

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:CAN CAUSE SEV IRRIT,
REDNESS, TEARING, BLURRED VISION. SKIN:PRLNGD/RPTD CONT CAN CAUSE
MOD IRRIT, DEFAT, DERM. INHAL:EXCESS INHAL OF VAPS CAN CAUSE NASAL
& RESP IRRIT, CNS EFTS INCLG DIZZ, W EAK, FATG, NAUS, HDCH & POSS
UNCON & EVEN DEATH. INGEST:CAN CAUSE GI IRRIT, NAUS, VOMIT & DIARR.
ASPIR(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:OF MATL INTO LUNGS CAN CAUSE CHEM
PNEUM WHICH CAN BE FATAL. CHRONIC:WHEN PRODS OF SIMILAR COMPOSITION
WERE TESTED ON LAB ANIMAL, WEAK TO MOD POS RSLTS WERE FOUND IN
MOUSE SKIN CANCER STUDIES, MIXED & INCONSISTENT RSLTS WERE FOUND
IN MUTAGENICITY STUDIES & NEG RSLTS WERE FOUND IN RAT TERATOLOGY
STUDIES.(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN:THORO WASH EXPOSED AREA W/SOAP & WATER. REMOVE CONTAMD
CLTHG. LAUNDER CONTAMD CLTHG BEFORE RE-USE. EYES:FLUSH W/LGE AMTS
OF WATER, LIFT UPPER & LOWER LIDS OCCAS, GET MED ATTN. INGEST:DO
NOT INDUC E VOMIT, KEEP PERS WARM, QUIET & GET MED ATTN. ASPIR OF
MATL INTO LUNGS DUE TO VOMIT CAN CAUSE CHEM PNEUM WHICH CAN BE
FATAL. INHAL: REMOVE PERS TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN
O*2. IF(SUPDAT)

Flash Point:>120F,>49C
Lower Limits:1.0%
Extinguishing Media:REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT & POSS ENDANGER
LIFE OF FIREFIGHTER, ESP IF (SUPDAT)
Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR
DRUM(EVEN EMPTY) BECAUSE PRODUCT(EVEN JUST RESIDUE) CAN IGNITE
EXPOS. VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND(SUPDAT)

Spill Release Procedures:SMALL:ABSORB LIQ ON PAPER, VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LGE:ELIM ALL IGNIT SOURCES(FLARES, FLAMES
INCLG PILOT LIGHTS, ELEC SPARKS). PERS NOT WEARING PROT EQUIP
SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN(ING
4)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES(VAPOR,
LIQUID &/SOLID), ALL HAZARD PRECS GIVEN IN THIS DATASHEET MUST BE
OBSERVED.

Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMP IS
EXCEEDED, A NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS ADVISED IN
ABSENCE OF PROPER ENVIRON CONTROL. OSHA REGS ALSO PERMIT OTHER
NIOSH/MSHA RESP (NEG PRESS TY PE) UNDER SPEC CNDTNS(SEE SAFETY(ING
8)
Ventilation:PROVIDE SUFFICIENT MECHANICAL(GENERAL &/LOCAL EXHAUST) VENT
TO MAINTAIN EXPOS BELOW TLV(S).
Protective Gloves:NITRILE RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA. IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: SPRAYED INTO CNTNRS OF HOT, BURNING LIQ. EXPLO HAZ: OR
BE MOVED BY VENT & IGNITED BY HEAT. EFTS OF OVEREXP: OVEREXP TO
MATL(OR ITS COMPONENTS) HAS BEEN SUGGESTED AS CAUSE OF FOLLOWING
EFTS IN HUMANS: CNS EFTS. FIRST AID PROC: BRTHG HAS STOPPED GIVE
ARTF RESP. KEEP PERS WARM, QUIET & GET MED ATTN.

Boiling Pt:B.P. Text:300F,149C
Vapor Pres:<12 @ 100F
Vapor Density:HVR/AIR
Spec Gravity:0.9 @ 68F
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:BLACK LIQUID SLURRY.
Percent Volatiles by Volume:35-40

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH: STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:SMALL: DEPOSIT IN A LANDFILL IN ACCORD W/LOCAL,
STATE & FEDERAL REGULATIONS. LGE: DESTROY BY LIQUID INCINERATION.
CONTAMD ABSORB MAY BE DEPOSITED IN A LANDFILL IN ACCORDANCE
W/LOCAL, STATE & FEDERAL R EGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.